Leighton Meester & Sebastian Stan – 2010
Leighton Meester became a well-known TV star thanks to her lead role in the hit series called Gossip Girl. Sebastian Stan, who you may know for starring in the MCU, had a guest role in the series and it looks like the two of them instantly connected when they met on set.
They became a couple in 2008 and made countless public appearances together. Sadly, they broke up in 2010, and Meester got married to actor Adam Brody in 2014. Stan hasn’t put a ring around any woman’s finger yet, but he looks like he’s enjoying his current relationship with girlfriend Alejandra Onieva.
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